Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 19, Pages 3777-3780Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00221h
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Two identical or different merocyanine dyes were tethered by a rigid diphenylacetylene spacer unit that enables the folding of the two dyes into co-facially p-stacked structures in solvents of low polarity. Whilst the solvent-dependent absorption spectra of homodimers of identical dyes are easily interpreted as H-aggregates by exciton theory, the spectra of the heterodimers constitute a novel and more interesting case.
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