Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 19, Pages 3840-3843Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10520j
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Funding
- University Grants Commission, New Delhi, India [19-6/2011(i)EU-IV]
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The proficiency of the cyclometalated iridium complexes [(eta(5)-C5Me5) IrCl(L1)] (1), [(eta(5)-C5Me5) IrCl(L2)] (2) and [(eta(5)-C5Me5) IrCl(L3)] (3) has been examined towards photochemical water oxidation. The involvement of Ir(IV/V) in the catalytic process has been explored via CV, UV/vis, XPS spectroscopic studies and appreciable TON relative to the theoretical value of 1 from GC.
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