4.7 Article

Cuboctahedron-based indium-organic frameworks for gas sorption and selective cation exchange

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 51, Pages 7978-7981

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc03497g

Keywords

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Funding

  1. 973 Program [2011CB932504]
  2. National Nature Science Foundation of China [51420105002, 21505101]
  3. Natural Science Foundation of Zhejiang Province [LQ16B010003]
  4. Yunnan Applied Basic Research Projects [2016FD099]
  5. Wenzhou University

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Me2NH2](3)[In-3(BTB)(4)]center dot 2DMF center dot 2DMA center dot 28H(2)O (InOF-9) is an anionic indium-organic framework based on nanosized cuboctahedrons, which is sustained by tetrahedral [In(COO) 4] nodes and 3-connected tricarboxylates. Although InOF-9 is structurally unstable when exposed to air, it exhibits excellent gas sorption capacity through a supercritical carbon dioxide activation process and selectively encapsulates guest methylene blue cations.

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