Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 95, Pages 13787-13790Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07649a
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Funding
- NSFC [21601071, 21471027, 21671034]
- NSF of Jiangsu Province [BK20160211]
- Natural Science Foundation of Jiangsu Normal University [15XLR012]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- TAPP
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Two unprecedented polytantalotungstates (POTTs), Cs16K16Na4- [Ta18P12W90(OH)(6)(H2O)(2)O-360] center dot 24H(2)O (1) and Cs26K2H2[Yb2Ta18-P12W90(OH)(6)(H2O)(16)O-360] center dot 52H(2)O (2) based on the largest {Ta-18} and {Ta18Yb2} clusters, respectively, were hydrothermally synthesized. A photocatalytic study revealed that 1 and 2 exhibit significant ultraviolet photocatalytic water splitting activity.
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