4.7 Article

Synthesis by free radical polymerization and properties of BN-polystyrene and BN-poly(vinylbiphenyl)

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 93, Pages 13616-13619

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc07332h

Keywords

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Funding

  1. National Science Foundation [CHE-1308517, 160904, CHE-1561153]
  2. LaMattina Family Graduate Fellowship in Chemical Synthesis
  3. Camille Dreyfus Teacher-Scholar Awards Program
  4. Direct For Mathematical & Physical Scien [1609043] Funding Source: National Science Foundation
  5. Division Of Chemistry [1308517] Funding Source: National Science Foundation

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Free radical polymerization of B-vinyl-and B-styryl-functionalized azaborinine monomers gives well-defined hybrid polymers that were fully characterized by multinuclear NMR and GPC analysis; their solubility, thermal characteristics, and photophysical properties are dramatically different from those of the all-carbon polystyrene analogues.

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