Journal
CHEMICAL COMMUNICATIONS
Volume 52, Issue 11, Pages 2378-2381Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5cc10071b
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Funding
- National Natural Science Foundation of China (NSFC) [21225103, 21471087, 21301105, 21221062]
- Beijing Natural Science Foundation [2144051]
- Specialized Research Fund for the Doctoral Program of Higher Education of China
- Tsinghua University Initiative Foundation Research Program, THSJZ [20131089204]
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By addition of excess acid into the reaction mixture, a series of organically-derived Anderson-type polyoxometalates, {[R1CR2(CH2O)(2)]CrMo6O18(OH)(4)}(3-), with diols as the ligands are reported herein. Such a diol functionalization mode not only works for some specific triol ligands but also can readily be extended to the diol ligands, which will greatly enrich the species of alkoxo-derivatized Anderson POM clusters.
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