4.7 Article

Syntheses and magnetic properties of a pyrimidyl-substituted nitronyl nitroxide radical and its cobalt(II) complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 52, Issue 28, Pages 5033-5036

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6cc00915h

Keywords

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Funding

  1. 973 Program [2013CB922102]
  2. NSFC [21522103, 21471077]
  3. NSF of Jiangsu province [BK20150017]
  4. Priority Academic Program Development of Jiangsu Higher Education Institutions
  5. Fundamental Research Funds for the Central Universities [020514380006]

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A new bis-bidentate nitronyl nitroxide radical with a pyrimidyl substituent group and two Co(II) complexes of this ligand were synthesized and characterized. Field-induced single-molecule magnet behavior was firstly observed in the nitronyl nitroxide radical-bridged complexes.

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