Journal
JOURNAL OF APPLIED POLYMER SCIENCE
Volume 137, Issue 44, Pages -Publisher
WILEY
DOI: 10.1002/app.49344
Keywords
biopolymers and renewable polymers; crystallization; fibers; polyamides
Categories
Funding
- NSFC-Liaoning Joint Fund [U1808211]
- Science and Technology Program of Beijing [Z181100004118001, Z191100007219009]
- Science and Technology Program of Liaoning Province [2019JH1/10100010]
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Bio-based polyamide 56 (PA56) fibers with the circular and trefoil cross-sections were prepared by high-speed spinning process. The pre-oriented yarns (POY) and draw-textured yarns (DTY) of PA56 were studied. The results showed that gamma phase crystal dominated in POY with relative high degrees in the crystallinity and crystal orientation. In DTY, the drawing effect made the crystal transform from gamma to alpha phase with the properties of the enhanced thickness of the crystal plate and the more order arranged molecules, that was the long period in these fibers was obviously increased to 7-8 nm. gamma to alpha phase transition was much easy for PA56 fibers with circular cross-section during drawing. PA56 fibers had excellent moisture absorption and release performances. They were easy to be dyed and had a good color fastness.
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