Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 822, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2020.153657
Keywords
Rare earth sesquioxide; X-ray diffraction; High pressure; Rietveld refinement; Strain anisotropy; Compressibility and equation of state
Categories
Funding
- Department of Atomic Energy (DAE), Government of India
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High pressure behavior of hexagonal rare earth sesquioxide La2O3 have been investigated using X-ray diffraction, Raman spectroscopy and first principle calculations. Though the hexagonal structure is stable up to 26.5 GPa, incompressibility along the a axis is visible above 9.7 GPa. Rietveld structure refinements in conjunction with the Stephans anisotropic strain broadening model revealed the onset of an atypical bond compression and modification in the relative intensities of the diffraction peaks at similar to 5.6 GPa. A significant increase in the intensity of 100 reflection and a clear reduction in the intensity of 103 reflection above 5.6 GPa suggests that pressure induces sliding of the adjacent La-O layers in opposite directions rather than compressing along the a axis. Further, a negative correlation of in-plane strain with pressure above 5.6 GPa indicate the layer sliding is accompanied by a reduction of in-plane strain in the hexagonal structure. Raman studies show the lifting of the degeneracy of the two stretching modes, in-plane E-g and out of plane A(1g), and the change of slope of omega vs. P curve for the two in-plane E-g modes at 3.6 GPa. First principle density functional theory calculation substantiates our experimental observations that the pressure induced anisotropic strain distribution is driving the system into low energy configurations. The Birch -Murnaghan equation of state fit to the experimental pressure-volume data yielded a bulk modulus value of B-0 = 102(5) GPa with B-0' = 9.8(1.0) for P <= 9.7 GPa, in good agreement with the 114 GPa of density functional theory calculations. (C) 2020 Elsevier B.V. All rights reserved.
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