4.7 Article

Combustion behaviors and explosibility of suspended metal hydride TiH2 dust

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 45, Issue 21, Pages 12216-12224

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.02.137

Keywords

Dust explosion; Hydrogen energy; Flame propagation speed; Explosion index; Metal hydride

Funding

  1. National Natural Science Foundation of China [11972046]
  2. Chinese Post Doctoral Fund [2017M610381, 2019T120536]

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In the production and storage processes of metal hydride material of TiH2, there are at least three kinds of explosion hazards, for example, TiH2 dust explosion, H(2 )explosion and hybrid H-2/TiH2 dust explosion. In this study, combustion behaviors of TiH2 dust cloud under isobaric and isochoric conditions were studied using a visual dust combustion facility and a standard 20-L spherical explosion vessel bomb, respectively, and Ti dust and hybrid H-2/Ti dust were used as the reference materials. Experimental results showed that at equal dust concentrations, the flame propagation speed S-f, burning velocity S-L, maximum pressure rise P(ex )and maximum rate of pressure rise (dP/dt)(ex) of TiH2 dust were all higher than those of Ti dust, while much smaller than those of hybrid H-2/Ti dust except the maximum pressure rise P-ex. The hydrogen state and content were the primary factors for the combustion differences of dust explosions. The values of explosion index K-st showed that the explosion risks of these samples increased as follows: Ti- < TiH2 (<) hybrid H-2/Ti dust. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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