Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 45, Issue 23, Pages 12629-12640Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.02.212
Keywords
NiCo-LDH; Oxygen evolution reaction; Interaction; Exfoliation; Electrocatalyst
Categories
Funding
- National Natural Science Foundation of China [51272187, 11704288]
- Science and Technology Supporting Program of Hubei province [2015BAA093, 2013CFA012]
- Wuhan Government [2016010101010026]
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The developments of inexpensive and efficient oxygen evolution reaction (OER) electro-catalysts without noble metals are very critical for energy conversion and storage systems. In this work, a series of NiCo-layered double hydroxide (NiCo-LDH) and NiCo oxides using co-precipitation and thermal treatment method have been successfully synthesized. Structural characterizations have been investigated by X-ray powder diffraction (XRD), Field emission scanning electron microscope (FE-SEM) equipped with energy-dispersive Xray mapping technology (EDS), Transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy respectively (XPS). By intercalating and eliminating CO33- an- ions in the layers of bulk NiCo-layered double hydroxide (NiCo-LDH), the as-present catalyst (NiCo-CH) exhibit remarkable advantages for OER performance, including porous nanostructures, high surface area, high content of Ni3+ and Co2+ on the surface and abundant active sites. With these favorable features, NiCo-CH shows a much better OER performance than that of other catalysts and commercial Pt/C, which has a low onset potential (1.51 V), a low overpotential (343 mV at 10mA/cm(-2)) and a small Tafel slope (66mWdec(-1)). Our work presents an effective strategy to controllably design and synthesize NiCo-LDH electrocatalysts with optimizable OER performances. (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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