4.7 Article

Tetraphenylethylene(TPE)-Containing Metal-Organic Nanobelt and Its Turn-on Fluorescence for Sulfide (S2-)

Journal

INORGANIC CHEMISTRY
Volume 59, Issue 9, Pages 6640-6645

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c00928

Keywords

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Funding

  1. National Natural Science Foundation of China [21971257]
  2. Hunan Provincial Science and Technology Plan Project of China [2019TP1001]
  3. Ministry of Science and Technology of Taiwan [MOST106-2628M-002-007MY3]

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A metal-organic supramolecular nanobelt was synthesized by quantitative self-assembling terpyridine-functionized tetraphenylethylene (TPE) and Cd2+, which only showed a weak emission both in solution or aggregated state. Nevertheless, nanobelt complex could be transferred to a fluorescence turn-on sensor to S2- by taking advantage of the structural transformation from nanobelt to its fluorescent ligand.

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