Journal
INORGANIC CHEMISTRY
Volume 59, Issue 8, Pages 5713-5720Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c00505
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Funding
- National Natural Science Foundation of China [21971208, 21771145]
- Fok Ying Tong Education Foundation [171010]
- State Key Laboratory of Luminescent Materials and Devices (South China University of Technology) [2019-skllmd-20]
- Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates (South China University of Technology) [2019B030301003]
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Tunable luminescent materials have attracted considerable interest for their wide applications in electronic optical devices, biological probes and sensors, tunable displays, and security technologies. Herein, we describe a strategy of coordination-driven self-assembly in order to prepare discrete tetraphenylethene-based platinum(II) bis-triangular dicycles 1 and 2 with aggregation-induced emission properties. The X-ray structure confirms that they possess two triangular cavities in which free rotation of the central TPE unit is restricted. As a kind of fluorescent material, the AIE-active dicycles have good emissions with wide tunability based on their aggregate states by changing different solvents, adjusting the temperature, or combining them with other dyes e.g., perylene via a co-assembly process.
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