Structural ordering and dielectric properties of Ba3CaNb2O9-based microwave ceramics

Ba3CaNb2O9 is a 1:2 ordered perovskite which presents a trigonal cell within the D-3d(3) space group. Dense ceramics of Ba3CaNb2O9 were prepared by the solid-state reaction route, and their microwave dielectric features were evaluated as a function of the sintering time. From Raman spectroscopy, by using group theory calculations, we were able to recognize the coexistence of the 1:1 and 1:2 ordering types in all samples, in which increasing the sintering time tends to reduce the 1:1 domain, leading to an enhancement of the unloaded quality factor. We concluded that this domain acts as a lattice vibration damping, consequently raising the dielectric loss at microwave frequencies. The best microwave dielectric parameters were determined in ceramics sintered at 1500 degrees C for 32h: epsilon' similar to 43; Q(u) x f(r) = 15,752 GHz; tau(f) similar to 278 ppm degrees C-1. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.