Journal
CEMENT & CONCRETE COMPOSITES
Volume 65, Issue -, Pages 83-93Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.cemconcomp.2015.10.016
Keywords
Self-healing; Self-sealing; Hydrogels; mu CT; EDX; High-performance concrete
Funding
- Research Foundation-Flanders (FWO-Vlaanderen) [1.1.D74.15N]
- Strategic Initiative Materials (SIM, program SHE)
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Autogenous healing of cracks may offer a solution for brittle cementitious materials. In this study, the healing building blocks are available through the well-designed ultra-ductile microfibre-reinforced mixture with a low water-to-binder ratio and water is available through the inclusion of superabsorbent polymers. As visual inspection demonstrates that the crack is completely closed at the surface, one may ask whether this healing also is present in the interior of the crack. X-ray computed micro-tomography was therefore used to study the extent of autogenous healing in cracked cylindrical specimens. It was found that the extent of autogenous healing in a cementitious material depends on the crack depth. Only near the crack mouth (0 till 800-1000 mu m) the crack is closed by calcium carbonate formation in case of wet/dry cycles. In combination with superabsorbent polymers, the extent of healing was more substantial. For mixtures containing superabsorbent polymers there was even partial healing in the interior of the crack when stored at a relative humidity of 60% or morethan 90%. Energy-dispersive spectroscopy combined with microscopic analysis showed that the healing products were mainly calcium carbonate. The smart cementitious material with superabsorbent polymers is thus an excellent material to use in future building applications as the healing capacity is improved. (C) 2015 Elsevier Ltd. All rights reserved.
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