Catalytic ozonation of dibutyl phthalate in the presence of Ag-doped NiFe2O4and its mechanism

In this study, NiFe(2)O(4)and Ag(0.1)Ni(0.95)Fe(2)O(4)were successfully prepared by the sol-gel method and applied to catalyze ozone for dibutyl phthalate (DBP) degrading. The synthesized catalysts were characterized by X-ray diffraction, Fourier-transform infrared spectroscopy, and vibrating sample magnetometer. The removal efficiency was compared with different catalyst dosage, pH condition, and initial DBP concentration for the two catalysts. The results showed that the introduction of Ag(0.1)Ni(0.95)Fe(2)O(4)enhanced the ozone decomposition and the utilization efficiency of ozone from 32.2% (ozone alone) to 56.5% and improved the degradation efficiency of DBP significantly. The two catalysts both presented good recycling performance. Furthermore, the scavenger test displayed DBP degradation by catalytic ozonation dominated by OH in this study. These insights into the catalytic ozonation mechanism on Ag(0.1)Ni(0.95)Fe(2)O(4)will advance their practical application to the catalytic degradation of organic pollutants.

Automated summary

NiFe(2)O(4) and Ag(0.1)Ni(0.95)Fe(2)O(4) were successfully prepared by sol-gel method and applied for ozone catalytic degradation of DBP. The introduction of Ag(0.1)Ni(0.95)Fe(2)O(4) significantly enhanced ozone decomposition and DBP degradation efficiency.