Journal
ENERGY CONVERSION AND MANAGEMENT
Volume 212, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.enconman.2020.112694
Keywords
Sorption thermochemical energy storage; Core-shell sorbents; Photothermal; Calcium chloride
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Funding
- National Natural Science Foundation of China [51176043]
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This study aimed to develop a novel sorbent for solar driven thermochemical heat storage. The core-shell CaCl2@C composites with tunable CaCl2 loading were obtained by a facile one-pot pyrolysis strategy, with the low-cost and abundant coal tar being used as the carbon precursor. CaCl2 was confined to the mesopores and macropores of the carbon shell, which led to a better structural stability than that of the impregnated sorbent. Moreover, the light-to-heat conversion of carbon shell was followed by the thermal energy storage by calcium chloride. In addition, the surface temperature of Ca/CT200-700 under the simulated sunlight of 1000 W/m(2) increased to 75 degrees C. After irradiation for 230 min, the volumetric energy storage density of Ca/CT200-700 was 254 kWh/m(3), with the water loss of 0.81 g-H2O/g-sorbent. This core-shell sorbent will provide new insights into the field of solar thermal conversion and storage.
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