Journal
CRYSTAL GROWTH & DESIGN
Volume 20, Issue 6, Pages 3601-3604Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.0c00336
Keywords
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Funding
- National Research Foundation of Korea (NRF) - Korean Government [MEST] [2016R1A2B3009532, 2016R1A5A1009405]
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Self-assembly of AgPF6 with a new C-3-symmetric tridentate N-donor ligand gives rise to unusual pseudo-2D porous networks with open channels via the interpenetration of 1D zigzag ladders. The open-channel networks selectively adsorb only m-xylene from the mixture of o- and m-xylene, with o-xylene thus acting as a channel-entrance stopper at room temperature. This system exemplifies unprecedented separation of o- and m-xylene.
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