Journal
CORROSION SCIENCE
Volume 166, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2019.108419
Keywords
Magnesium; EIS; Weight loss; Pitting corrosion; Anodic dissolution
Funding
- National Key Research and Development Program of China [2017YFB0305504]
- Fundamental Research Funds for the Central Universities [N180904006]
- National Natural Science Foundation of China [51971054]
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The corrosion behavior and mechanism of as-cast and as-extruded Mg-Zn-Gd-Zr alloys with specific ternary phases are investigated using scanning electron microscope (SEM), scanning Kelvin probe force microscope (SKPFM), immersion and electrochemical tests. Lamellar X-Mg12GdZn, net-like W-Mg3Gd2Zn3 and strip-like I-Mg3Zn6Gd phases form successively. The eutectic W-phase owns the highest potential difference of 120 mV with Mg matrix, accelerating micro-galvanic corrosion. Continuously distributed and undersized I-phase leads to uniform corrosion. The as-extruded Mg-3Zn-11Gd-0.6 Zr alloy exhibits superior corrosion resistance, due to the relatively low potential difference between X-phase and matrix, the corrosion barrier effect and typical {0002} < 10 - 10 > texture components.
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