4.7 Article

A biomass based photonic crystal made of konjac tofu

Journal

CHINESE CHEMICAL LETTERS
Volume 32, Issue 1, Pages 587-590

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2020.03.012

Keywords

Photonic crystals; Konjac glucomannan; Hydrogel; Interpenetrating double network; Sensor

Funding

  1. National Natural Science Foundation of China [21874009, 21804009]

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A double network polymeric film was created by crosslinking KGM and PVA under acidic conditions, improving the hydrogel's mechanical properties and solvent resistance; A biomass-based photonic crystal produced is sensitive to methanol and has the ability to detect it in gasoline, showing promising applications.
Konjac tofu is a traditional Chinese food whose main ingredient is the water-soluble polysaccharide from konjac tubers-konjac glucomannan (KGM). Herein we report an interpenetrating double network polymeric film by crosslinking KGM and polyvinyl alcohol (PVA) with glutaraldehyde under acidic conditions. PVA was introduced into the hydrogel system as a hard skeleton, which not only maintained the biocompatibility of KGM, but also gave the hydrogel superior mechanical properties and solvent resistance. Implanting a colloidal array inside the above film, we obtained a new type of biomass based photonic crystal that is sensitive to a variety of physical and chemical stimulus, especially for methanol. This photonic crystal responds to methanol and methanol vapor, and has the ability to detect methanol in gasoline, which has a good application prospect. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

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