Fe(II) activated persulfate assisted hydrothermal conversion of sewage sludge: Focusing on nitrogen transformation mechanism and removal effectiveness

In this study, Fe(II)-activated persulfate-assisted hydrothermal treatment (Fe(II)-PS-HT) was used to improve the efficiency of removing nitrogen (N) from the sewage sludge (SS) under relatively mild conditions (i.e., at 150 degrees C, for 20min), and the N transformation mechanism was investigated. The total N content in the solid residue was used to evaluate the N removal efficiency. Further, the redistribution of N in the solid and liquid products was characterized and quantified to obtain a N transformation mechanism during sequential persulfate oxidation (Fe(II) and persulfate) assisted hydrothermal treatment (HT). The experimental results denote that the N removal efficiency obtained from the Fe(II)-PS-HT (persulfate/C = 0.085 and Fe(II)/persulfate = 0.5) treated SS was increased by 35.0% at a relatively mild temperature (i.e., 150 degrees C) when compared with that obtained by treating SS using normal HT. Elevating Fe(II)/persulfate ratio to 1.25 promoting the N removal efficiency by 59.9%-65.9%. Furthermore, the electron paramagnetic resonance (EPR) and scanning electron microscopy (SEM) results clearly denote a N removal mechanism where the sulfate radicals (SO4 center dot-) produced by Fe(II)-PS destroy the sludge structure and destructed extracellular polymers (EPS). In the absence of EPS protection, proteins were directly exposed to extreme hydrothermal circumstances, and were rapidly transformed from the SS into the liquid residue. The free radicals also provided energy for the denitrification of Heterocycle-N. Consequently, a high N removal efficiency was obtained by Fe(II)-PS-HT with persulfate/C = 0.085 and Fe(II)/persulfate = 1.25 at 150 degrees C for 20 min. (C) 2019 Elsevier Ltd. All rights reserved.