Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 30, Pages 6894-6898Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202000911
Keywords
cluster compounds; lead; perovskites; solar cells; titanium
Categories
Funding
- NSFC [21673238, 21922111, 21801104]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Natural Science Foundation of Fujian Province [2017J06009]
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In this work we have successfully prepared two lead-doped titanium-oxo clusters with core structures that resemble isolated perovskite PbTiO3 species. In the obtained highly symmetric Pb8Ti7-oxo cluster, the central TiO6 octahedra are orthogonally extended to adjacent octahedra through corner-sharing and the eight dopant lead ions form a cubic arrangement, making it the first molecular model of perovskite PbTiO3. Moreover, the clusters readily dissolved in chloroform and showed high solution stability, as confirmed by MALDI-TOF MS measurements. Based on such solution processability, they can be easily spin-coated to form homogeneous films, which were employed as electron-transport materials in perovskite solar cells to give an average power conversion efficiency of around 15 % and improved device stability. This newly developed bottom-up cluster assembly method provides an efficient approach to the construction of atomically precise models of perovskite metal oxides as well as potential molecular tools to extend their applications.
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