Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 43, Pages 9471-9474Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202001119
Keywords
addition; alkynes; arenes; aromatization; dienes
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Funding
- JSPS [19K05481, 17K19127]
- Tokuyama Science Foundation
- UBE Foundation
- Grants-in-Aid for Scientific Research [19K05481, 17K19127] Funding Source: KAKEN
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Facile synthesis of various benzonaphthofurans was achieved by intramolecular hydroarylation of 1,4-disilyl-2-aryloxy-1,3-enynes followed by cycloaddition with arynes or alkenes and finally desilylaromatization. The three-step transformation can be operated sequentially in one-pot, providing with a range of furanoacenes easily and highly effectively.
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