Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 26, Issue 45, Pages 10210-10212Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202001471
Keywords
carbon allotrope; helicene; hexabenzocoronene; nanographene; polycyclic aromatic hydrocarbons
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Funding
- Deutsche Forschungsgemeinschaft (DFG) [182849149-SFB 953]
- Fonds der Chemischen Industrie (FCI)
- Graduate School Molecular Science (GSMS)
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A synthetic route towards a novel hexabenzocoronene-based helical nanographene motif was developed. A hexaphenylbenzene precursor was therefore designed, which cannot undergo, due to steric restrictions, a complete planarization reaction. This precursor was transformed under oxidative cyclodehydrogenation conditions to a pi-extended [5]helicene, which was fully characterized including X-ray diffraction analysis.
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