Journal
CHEMISTRY LETTERS
Volume 49, Issue 7, Pages 867-869Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.200297
Keywords
Organocatalyst; Michael reaction; Domino reaction
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Funding
- JSPS KAKENHI [JP20H04801, JP19H05630]
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Substituted chiral hydrindanes were synthesized as single isomers in almost enantiopure forms through a one-pot process that proceeds via the diphenylprolinol silyl ether mediated-domino Michael/Michael reaction of alpha,beta-unsaturated aldehydes and 3-hexene-2,5-dione, and a subsequent intramolecular aldol condensation of the generated cyclopentanone intermediate.
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