Journal
CHEMICAL ENGINEERING JOURNAL
Volume 398, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2020.125681
Keywords
Core-shell catalyst; Heterogeneous electro-Fenton; Metal-organic frameworks; Internal micro-electrolysis; Sulfamethazine degradation
Categories
Funding
- Natural Science Foundation of China [21773129, 21976096, 21811530274, 21273120]
- Nankai University-Cangzhou Bohai New Area Green Chemical Research Institute Cultivation Fund
- Tianjin Development Program for Innovation and Entrepreneurship
- Tianjin Post-graduate Students Research and Innovation Project [2019YJSB075]
- 111 program, Ministry of Education, China [T2017002]
- Fundamental Research Funds for the Central Universities
- Tianjin Science and Technology Program [19PTZWHZ00050]
Ask authors/readers for more resources
Core-shell structured hybrid octahedron, which contained a Fe-based nanoparticle core (Fe/Fe3C) and a graphitized porous carbon (PC) shell (Fe/Fe3C@PC), prepared through one-pot pyrolysis using MIL-101(Fe) as the sacrificial template, was used as a novel catalyst for the degradation of sulfamethazine (SMT) by heterogeneous electro-Fenton (Hetero-EF). Fe/Fe3C@PC outperformed common heterogeneous catalysts such as Fe-0, Fe3O4 and Fe2O3 due to the synergistic effect between Fe/Fe3C nanoparticles and PC. The rate constant for SMT degradation in the Hetero-EF process was 7.17-folds of that in the heterogeneous Fenton (Hetero-F) process. The plausible catalytic mechanism and degradation pathway for mineralization of SMT by this Hetero-EF process were proposed, confirming the main role of surface-bound hydroxyl radical ((OHads)-O-center dot) oxidation. Moreover, internal-micro-electrolysis (IME)-enhanced Hetero-EF reaction was verified by experiments and density functional theory (DFT) calculations. Fe/Fe3C@PC could be easily recycled due to magnetism and well recovered via a simple thermal treatment in H-2 atmosphere. This work enlightened metal-organic frameworks (MOFs) derived core-shell structured hybrids to be ultra-efficient heterogeneous catalysts and their catalytic mechanism promoting promising utilization in the Hetero-EF process for organic pollutants removal.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available