Journal
CHEMICAL ENGINEERING JOURNAL
Volume 385, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.123838
Keywords
Sb2S3; Sb2Se3; Nanodots; Potassium-ion batteries
Categories
Funding
- National Natural Science Foundation of China [51904342, 51622406, 21673298]
- Young Elite Scientists Sponsorship Program by CAST [2017QNRC001]
- National Postdoctoral Program for Innovative Talents [BX201600192]
- Central South University Postdoctoral Foundation [140050018]
- China Postdoctoral Science Foundation [2017M6203552]
- National Key Research and Development Program of China [2017YFB0102000, 2018YFB0104200]
- Hunan Provincial Science and Technology Plan [2017TP1001]
- Fundamental Research Funds for the Central Universities of Central South University [2019zzts431, 2019zzts433]
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Antimony-based materials with high theoretical capacity have been considered as a promising anode materials for potassium-ion batteries (PIBs). Unfortunately, the large volume expansion leads to rapid capacity fading and poor rate capability. In this work, Sb2S3 (Sb2Se3) nanodots/carbon composites are constructed through pyrolysis and co-sulfurization (selenylation) process of sodium stibogluconate for the first time. In the composite, Sb2S3 (Sb2Se3) nanodots with diameters of 15-25 nm are uniformly inlaid into S(Se)-doped carbon skeleton. Notably the ultrafine nanodots can remarkedly shorten the ions diffusion distance with enhanced kinetic process. Also the S(Se)-doped carbon would provide the stable structure support and conducive path. When applied as the anode for PIBs, they all show satisfactory potassium-storage properties in terms of high reversible capacity and superior rate capability, especially the excellent electrochemical performances of Sb2Se3 nanodots/carbon with a reversible capacity of 312.03 mAh g(-1) at 1000 mA g(-1) after 200 cycles, which can be attributed to the synergistic effect of nanodots and doped carbon, minimizing potassiation-induced deformations and facilitating the reversible adsorption of K ions. More importantly, the volume changes during the K+ intercalation/deintercalation process have been analyzed in details, which is well consistent with the result of electrochemical performance, as expected.
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