Journal
CHEMCATCHEM
Volume 12, Issue 13, Pages 3463-3466Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202000652
Keywords
Synthetic methods; Multicomponent reaction; Sulfonamide; Palladium; Amino acid
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Funding
- DFG [6093/4-1]
- research unit NanoKat (TU Kaiserslautern)
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A palladium-catalyzed three-component synthesis of alpha-arylglycines from benzoic acids, sulfonamides and glyoxylic acid is reported. This novel reaction offers straightforward access to the important arylglycine motif in good yields and high structural diversity. By replacing boronic with carboxylic acids as nucleophilic component, this method can be considered as a more sustainable version of the classical Petasis reaction for synthesis of arylglycines.
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