Journal
CHEMBIOCHEM
Volume 21, Issue 16, Pages 2232-2240Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cbic.202000072
Keywords
Ion spectroscopy; Mass spectrometry; Photocatalysis; Photochemistry; Reaction intermediates
Funding
- European Research Council (ERC CoG) [682275]
- Netherlands Organization for Scientific Research (NWO) [740.018.022]
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This Minireview highlights the application of electrospray ionization mass spectrometry (ESI-MS) to investigating photochemical reactions. We show possible approaches to on-line ESI-MS monitoring of photocatalytic reactions and give examples of the characterization of short-lived photochemical intermediates by ion spectroscopy. The minireview also exemplifies in-depth mass spectrometric studies of photoisomerization reactions and photofragmentation reactions. Apart from mechanistic studies, the coupling of photochemistry and mass spectrometry is a powerful approach to studying structure and properties of biomolecules. We show several examples focused on investigation of intrinsic properties of model biomolecules.
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