Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 93, Issue 9, Pages 1065-1069Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20200122
Keywords
Base catalyst; Organoboron; 1,2-Addition
Categories
Funding
- JSPS KAKENHI [JP17H06449, JP18H01971]
- Kanazawa University SAKIGAKE project 2018
Ask authors/readers for more resources
The KHMDS-catalyzed tertiary alkylation of aldehydes, ketones or imines using tertiary benzylic organoboronates is reported. This protocol permitted the use of tertiary benzylic alkylboronates as the tertiary alkyl anion for construction of highly congested contiguous sp(3) carbon centers. The mild and transition-metal-free reaction conditions are attractive features of the protocol.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
