4.7 Article

Study of pitting corrosion inhibition effect on aluminum alloy in seawater by biomineralized film

Journal

BIOELECTROCHEMISTRY
Volume 132, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.bioelechem.2019.107408

Keywords

Pitting corrosion inhibition; Aluminum alloy; Biomineralized film; Seawater; Electrochemical impedance

Funding

  1. National Key Research and Development Program [2016YFB0300700]
  2. National Natural Science Foundation [51609133, 5162195]
  3. China Postdoctoral Science Foundation [2017M620153]

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Metallic materials can be easily corroded in marine environments, in which pitting corrosion is very common. In this study, we investigated the effect of Bacillus subtilis, isolated from the South China Sea on the corrosion behavior of 2A14 aluminum alloy in seawater. Surface analysis of the alloy in the presence of the bacteria was used to observe corrosion morphology and the corrosion products studied. Electrochemical method was used to analyze the corrosion susceptibility of the alloy in seawater in the presence of the bacteria. Surface analysis suggested that a protective film with CaMg(CO3)(2) was gradually formed on the surface of the alloy in the presence of the bacteria. The electrochemical results showed that the radius of the impedance arc of the alloy immersed in seawater with bacteria increased gradually with time. The bacteria promoted the formation of the CaMg(CO3)(2) film, which blocked seawater from the alloy and consequently, inhibited pitting corrosion. (C) 2019 Published by Elsevier B.V.

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