Journal
BIOCHEMICAL ENGINEERING JOURNAL
Volume 156, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.bej.2020.107497
Keywords
Biosynthesis; CdSe; Quantum dots; R. mucilaginosa PA-1; Photocatalysis
Funding
- National Natural Science of Foundation of China [31670126, 31770139]
- Natural Science Foundation of Anhui Province of China [1508085ME92, 1608085QC47]
- Scientific Research Foundation of Talented Scholars from Anhui University [J01006042]
- Open Fund for Discipline Construction, Institute of Physical Science and Information Technology, Anhui University [S01003121]
- Supporting Plan for Excellent Young Talents in Colleges of Anhui Province [gxyqZD2017002, gxyq2018001]
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CdSe quantum dots (QDs) are semiconductor materials and possess unique optical and electronic properties, therefore being increasingly used in many fields. Biosynthesis of CdSe QDs has several advantages over the chemical synthesis route. In this study, the CdSe QDs were biosynthesized using a yeast Rhodotorula mucilaginosa PA-1 under the aerobic condition. The regulation of QDs biosynthesis was achieved by changing the concentration of precursors and the pH of the medium. The concentration of cadmium ions but not selenium ions determined the synthesis of CdSe QDs. Synthesized CdSe QDs with a narrow size distribution (3.2 +/- 0.4 nm) exhibited great photocatalytic activity under ultraviolet and visible light using a dye malachite green (MG) as a model pollutant. The photocatalytic degradation efficiency of MG was 86.5 % and 94.28 % after 60 min irradiation under ultraviolet and visible light, respectively, which is comparable for those catalyzed by various nanomaterials through chemical synthesis.
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