Journal
CATALYSIS COMMUNICATIONS
Volume 83, Issue -, Pages 82-87Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2016.05.017
Keywords
Aerobic oxidation; Alcohol; tert-Butyl nitrite (TBN); N-Hydroxyphthalimide (NHPI)
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A highly practical metal-free catalytic system has been developed for aerobic oxidation of alcohols to corresponding ketones and aldehydes using catalytic amount of N-hydroxyphthalimide (NHPI) and tert-butyl nitrite (TBN) with molecular oxygen serving as the terminal oxidant. A variety of aliphatic, aromatic, allylic, and heterocyclic alcohols were smoothly converted to desired products with moderate to excellent yields. Moreover, a possible radical mechanism was proposed. (C) 2016 Elsevier B.V. All rights reserved.
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