Cat in a bag recycling of dendrimer encapsulated Au nanoparticles by use of dialysis membrane bag in the reduction of 4-nitrophenol: proof of heterogeneous catalysis

Generation 4 PAMAM-NH2 dendrimers were used as template to synthesize Au-13- and Au-100-dendrimer-encapsulated nanoparticles (Au-DENS) with an average diameter of 2.1 +/- 03 and 3.1 +/- 0.5 nm respectively. Au-DENs were characterized using various techniques. Catalytic recycling of Au-DENs using a dialysis membrane bag in the reduction of 4-NP is presented. The reduction process was primarily monitored by UV-vis spectroscopy at around lambda 400 nm. The catalyst was found to exhibit a very good activity and stability even after more than 3 catalytic reaction cycles without any leaching, confirming that the reduction of 4-NP is purely a heterogeneous reaction. (C) 2016 Elsevier B.V. All rights reserved.