Journal
CATALYSIS COMMUNICATIONS
Volume 73, Issue -, Pages 46-49Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.catcom.2015.10.010
Keywords
Dimethyl oxalate; Methyl glycolate; Hydrogenation; Ni2P
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Funding
- Major State Basic Research Development Program of China (973 Program) [2012CB215305]
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An effective and stable bifunctional Ni2P/TiO2 catalyst was proposed for gas-phase hydrogenation of dimethyl oxalate to corresponding alcohols. A 93.0% conversion of DMO with a selectivity of 88.0% to methyl glycolate was observed under 210 degrees C. Moreover, the catalyst showed an excellent stability which can be performed for 3600 h under the reaction conditions of 230 degrees C, 3 MPa H-2 and the weight space velocity of 0.1 h(-1). (C) 2015 Elsevier B.V. All rights reserved.
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