Journal
CATALYSIS COMMUNICATIONS
Volume 78, Issue -, Pages 17-21Publisher
ELSEVIER
DOI: 10.1016/j.catcom.2016.01.034
Keywords
Metal-organic framework derived porous carbon; AgPd bimetal; Formic acid; Dehydrogenation
Categories
Funding
- Natural Science Foundation of Hebei Province [B2015204003]
- Natural Science Foundation of Agricultural University of Hebei [LG201404, ZD201506]
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An efficient synergistic catalyst, AgPd bimetal supported on metal-organic framework derived porous carbon (AgPd/MOF-5-C), was fabricated for the first time. The catalyst exhibited 100% H-2 selectivity and high catalytic activity in hydrogen generation from formic acid at ambient conditions. The initial turnover frequency could reach as high as 854 h(-1). The combination of distinct interaction among bimetal, support and high dispersion of nanoparticles drastically enhances the catalytic performance of the resulted catalyst. (C) 2016 Elsevier B.V. All rights reserved.
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