Journal
APPLIED SURFACE SCIENCE
Volume 509, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2020.145296
Keywords
Two-dimensional ultra-thin nanosheets; Z-scheme system; Sandwich structure; Photocatalytic hydrogen evolution
Categories
Funding
- National Natural Science Foundation of China [51672081]
- Natural Science Foundation of Hebei Province, China [B2018209356]
- One Hundred Excellent Talents of Innovation in Hebei Provincial Universities (III) [SLRC2017049]
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In this work, we report a sandwich structure of PANI-Ag-CN photocatalyst, which is stacked layer by layer with g-C3N4 and PANI ultra-thin two-dimensional nanosheets and Ag nanoparticles are embedded as interlayers. The Z-scheme heterojunction can be formed in this sandwich structure of PANI-Ag-CN photocatalyst, where Ag nanoparticles act as the charge transfer intermediate, leading to the annihilation of the holes of g-C3N4 and the electrons of PANI, and thus the strong reductive electrons and the strong oxidative holes can be left at the CB of g-C3N4 and VB of PANI, respectively. Meanwhile, the short charge transfer and the large number of active sites on the ultra-thin two-dimensional nanosheets are proved beneficial for to the photocatalytic hydrogen evolution from water. The PANI-Ag-CN photocatalyst exhibits an increased hydrogen evolution activity of 5048 mu mol.g(-1).h(-1), which is 43.52-fold higher than that of g-C3N4 and 58.02-fold higher than that of bulk g-C3N4. Moreover, the photocurrent of PANI-Ag-CN is 1.9 x 10(-6) A/cm(2), which is 5.94 times higher than that of g-C3N4.
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