4.6 Article

Tandem hydroformylation/isomerization/hydrogenation of bio-derived 1-arylbutadienes for the regioselective synthesis of branched aldehydes

Journal

APPLIED CATALYSIS A-GENERAL
Volume 598, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.apcata.2020.117583

Keywords

Tandem catalysis; Hydroformylation; Fragrance

Funding

  1. CAPES-COFECUB [PHC 884-17-France]
  2. INCT-Catalise
  3. CNPq [C627]

Ask authors/readers for more resources

The rhodium-catalyzed hydroformylation of 1-arylbutadienes derived from lignocellulosic bio-resources has been carried out in toluene and green solvents. In the presence of DPPE and XANTPHOS ligands, a regioselective Markovnikov Rh-H insertion takes place resulting in branched aldehydes in high selectivity, which contrasts with previous results obtained from aliphatic conjugated dienes. Depending on the nature of the diphosphine ligand, conjugated enals or saturated aldehydes are obtained in good to excellent selectivity. The later have a potential interest for fragrance industry, as they are homologous to commercial fragrance ingredients.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available