Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 34, Pages 14621-14627Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202005840
Keywords
covalent assembly; lithium-ion batteries; MoS(2)nanosheets; SnS nanodots; sodium-ion batteries
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Funding
- National Natural Science Foundation [51972235, 21703185]
- Natural Science Foundation of Shanghai [17ZR1447800]
- Leading Project Foundation of Science Department of Fujian Province [2018H0034]
- Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning, Shanghai Innovation Program [13ZZ026]
- Hundred Youth Talent Plan of Tongji University
- Fundamental Research Funds for the Central Universities
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Weak van der Waals interactions between interlayers of two-dimensional layered materials result in disabled across-interlayer electron transfer and poor layered structural stability, seriously deteriorating their performance in energy applications. Herein, we propose a novel covalent assembly strategy for MoS(2)nanosheets to realize unique MoS2/SnS hollow superassemblies (HSs) by using SnS nanodots as covalent linkages. The covalent assembly based on all-inorganic and carbon-free concept enables effective across-interlayer electron transfer, facilitated ion diffusion kinetics, and outstanding mechanical stability, which are evidenced by experimental characterization, DFT calculations, and mechanical simulations. Consequently, the MoS2/SnS HSs exhibit superb rate performance and long cycling stability in lithium-ion batteries, representing the best comprehensive performance in carbon-free MoS2-based anodes to date. Moreover, the MoS2/SnS HSs also show excellent sodium storage performance in sodium-ion batteries.
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