Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 32, Pages 13335-13340Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202003759
Keywords
f-block chemistry; inorganic; magnetization dynamics; organometallic; single-molecule magnet
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Funding
- National Science Foundation [CHE-1753014]
- Welch Foundation [A-1880]
- Fonds Wetenschappelijk Onderzoek Vlaanderen (FWO, Flemish Science Foundation)
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We report the first f-block-ruthenocenophane complexes 1 (Dy) and 2 (Tb) and provide a comparative discussion of their magnetic structure with respect to earlier reported ferrocenophane analogues. While axial elongation of the rare trigonal-prismatic geometry stabilizes the magnetic ground state in the case of Dy3+ and results in a larger barrier to magnetization reversal (U), a decrease in U is observed for the case of Tb3+.
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