Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 37, Pages 15933-15936Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202006293
Keywords
allylic alkylation; CuPd nanoparticles; electrocatalysis; organic electrosynthesis
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Funding
- American Chemical Society Petroleum Research Fund [57114-ND5]
- Center for the Capture and Conversion of CO2, a Center for Chemical Innovation - National Science Foundation [CHE-1240020, CHE-1464538]
- National Science Foundation Graduate Research Fellowship [1644760]
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An efficient CuPd nanoparticle (NP) catalyst (3 nm CuPd NPs deposited on carbon support) is designed for catalyzing electrochemical allylic alkylation in water/isopropanol (1:1 v/v) and 0.2 mKHCO(3)solution at room temperature. The Pd catalysis was Pd/Cu composition-dependent, and CuPd NPs with a Pd/Cu ratio close to one are the most efficient catalyst for the selective cross-coupling of alkyl halides and allylic halides to form C-C hydrocarbons with product yields reaching up to 99 %. This NP-catalyzed electrochemical allylic alkylation expands the synthetic scope of cross-coupling reactions and can be further extended to other organic reaction systems for developing green chemistry electrosynthesis methods.
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