Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 31, Pages 12623-12634Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202002518
Keywords
atropisomers; axial chirality; enantioselective catalysis
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Funding
- Zhejiang University of Technology
- Aix-Marseille Universite
- Centre National de la Recherche Scientifique (CNRS)
- Centrale Marseille
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Atropisomers possessing multiple stereogenic axes are intriguing molecules with huge potential. However, only few approaches for their enantioselective synthesis are available due to the difficulties in assembling various stereogenic axes with high enantiocontrol. Only recently, innovative methods have emerged, opening new possibilities for the synthesis of this original class of atropisomeric compounds. This Minireview describes the development of this field based on a classification of the multi-axis systems according to the distance between the stereogenic axes and the strategy used to build them.
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