Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 33, Pages 13879-13884Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202004235
Keywords
ferroelectric materials; perovskites; phase transition; X-ray detection
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Funding
- National Natural Science Foundation of China [21622108, 21875251, 21833010, 21525104]
- NSF of Fujian Province [2018H0047]
- Strategic Priority Research Program of the CAS [XDB20010200]
- Youth Innovation Promotion of CAS [2014262]
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Although two-dimensional (2D) metal-halide double perovskites display versatile physical properties due to their huge structural compatibility, room-temperature ferroelectric behavior has not yet been reported for this fascinating family. Here, we designed a room-temperature ferroelectric material composed of 2D halide double perovskites, (chloropropylammonium)(4)AgBiBr8, using an organic asymmetric dipolar ligand. It exhibits concrete ferroelectricity, including a Curie temperature of 305 K and a notable spontaneous polarization of approximate to 3.2 mu C cm(-2), triggered by dynamic ordering of the organic cation and the tilting motion of heterometallic AgBr6/BiBr6 octahedra. Besides, the alternating array of inorganic perovskite sheets and organic cations endows large mobility-lifetime product (mu tau=1.0x10(-3) cm(2) V-1) for detecting X-ray photons, which is almost tenfold higher than that of CH3NH3PbI3 wafers. As far as we know, this is the first study on an X-ray-sensitive ferroelectric material composed of 2D halide double perovskites. Our findings afford a promising platform for exploring new ferroelectric materials toward further device applications.
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