Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 59, Issue 24, Pages 9355-9359Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202001508
Keywords
catalysis; epoxides; light; radicals; titanocenes
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Funding
- Chinese Scholarship Council
- Deutsche Forschungsgemeinschaft [Ga 619/12-1]
- National Science Foundation [CHE-1565741]
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Irradiation of Cp2TiCl2 with green light leads to electronically excited [Cp2TiCl2]*. This complex constitutes an efficient photoredox catalyst for the reduction of epoxides and for 5-exo cyclizations of suitably unsaturated epoxides. To the best of our knowledge, our system is the first example of a molecular titanium photoredox catalyst.
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