Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 362, Issue 11, Pages 2254-2259Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202000314
Keywords
Carbonylation; multi-component reaction; photooxidative catalysis; radical/polar; silicates
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Funding
- JSPS [19H02722, 17K05866]
- MEXT [2707, JP15H05850]
- Sorbonne University [ANR-17-CE07-0018]
- MOST, Taiwan
- Grants-in-Aid for Scientific Research [17K05866, 19H02722] Funding Source: KAKEN
- Agence Nationale de la Recherche (ANR) [ANR-17-CE07-0018] Funding Source: Agence Nationale de la Recherche (ANR)
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Alkyl radicals, from primary to tertiary, formed by photocatalyzed oxidation of organosilicates, are involved efficiently in radical carbonylation with carbon monoxide (CO), in the presence of various amines and CCl4, leading to a variety of amides in moderate to good yields.
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