Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 30, Issue 24, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202000456
Keywords
asymmetric structures; chlorine substitution; open-circuit voltage; organic solar cells; small molecular acceptors
Categories
Funding
- National Natural Science Foundation of China [51763017, 21602150, 51425304, 51863012, 21861025, 51833004]
- Shen Zhen Technology and Innovation Commission [JCYJ20170413173814007, JCYJ20170818113905024]
- Hong Kong Research Grants Council [R6021-18, 16305915, 16322416, 606012, 16303917]
- Hong Kong Innovation and Technology Commission [ITC-CNERC14SC01, ITS/471/18]
- FCT - Fundacao para a Ciencia e a Tecnologia [UID/EMS/00481/2019-FCT]
- Centro Portugal Regional Operational Programme (Centro2020), under the PORTUGAL 2020 Partnership Agreement, through the European Regional Development Fund (ERDF) [CENTRO-01-0145-FEDER-022083]
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Small-molecule acceptors (SMAs)-based organic solar cells (OSCs) have exhibited great potential for achieving high power conversion efficiencies (PCEs). Meanwhile, developing asymmetric SMAs to improve photovoltaic performance by modulating energy level distribution and morphology has drawn lots of attention. In this work, based on the high-performance SMA (Y6), three asymmetric SMAs are developed by substituting the fluorine atoms on the terminal group with chlorine atoms, namely SY1 (two F atoms and one Cl atom), SY2 (two F atoms and two Cl atoms), and SY3 (three Cl atoms). Y6 (four F atoms) and Y6-4Cl (four Cl atoms) are synthesized as control molecules. As a result, SY1 exhibits the shallowest lowest unoccupied molecular orbital energy level and the best molecular packing among these five acceptors. Consequently, OSCs based on PM6:SY1 yield a champion PCE of 16.83% with an open-circuit voltage (V-OC) of 0.871 V, and a fill factor (FF) of 0.760, which is the best result among the five devices. The highest FF for the PM6:SY1-based device is mainly ascribed to the most balanced charge transport and optimal morphology. This contribution provides deeper understanding of applying asymmetric molecule design method to further promote PCEs of OSCs.
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