Zero-Dimensional Ordered Sr2CoMoO6-δ Double Perovskite as High-Rate Anion Intercalation Pseudocapacitance

In quest of a stable structure throughout redox reactions, an approach of B-site ordering (0D arrangement) of cations in double perovskites is adopted. Here, we report B-site cation ordering in double perovskite Sr-2 CoMoO6-delta (DP-SCM) that tends to a favorable rock salt structure (0D arrangement). The synergy of Co/Mo having good redox ability further facilitates high oxygen mobility. A high content of oxygen vacancy examined using XPS and EPR facilitates a high oxygen anion diffusion rate (2.03 X 10(-11) cm(2) s(-1)) Moreover, fast kinetics (Delta E-P approximate to 0.013 V@ 1 mV s(-1)) of charge storage prohibits any phase transformation reflecting the excellent cycle life (125% retention up to 5000 cycles). Such fast kinetics is majorly furnished from anion intercalation with little involvement from double layer mechanism (C-dl approximate to 42.1 F g(-1)). DP-SCM achieves a resultant capacitance of 747 F g(-1)@ 1 A g(-1) with a rate capability of 56% up to 10 A g(-1). Motivated by outstanding performance of DP-SCM electrodes, a symmetric cell is assembled with a 1.4 V operating potential that delivers a high energy density of 64 Wh kg(-1)@855 W kg(-1). This work on double perovskites suggests that the advance understanding of cation ordering and charge storage mechanism can provide a new direction to fabricate highly capacitive electrode materials.