Journal
COLLOID AND INTERFACE SCIENCE COMMUNICATIONS
Volume 34, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.colcom.2019.100231
Keywords
Emulsified oil; Sepiolite; Adsorption; Surfactant
Funding
- National Natural Science Foundation of China [21677087]
- National Science and Technology Major Project of China [2016ZX05040-005]
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Electrostatic adsorption and hydrophobicity constitute the main functions of effective removal of emulsified oils (EOs) in produced water. Here, sepiolite (Sep) is modified with single-chain and double-chain organic cation surfactants, stearyl trimethyl ammonium bromide (STAB) and dimethyl dioctadecyl ammonium bromide (DDAB). Analyses of SEM, CA and zeta-potential indicated that individually-dispersed Sep fibers modified to form Sep fibrous aggregates with a more hydrophobic and electropositive surface, which greatly improved EOs adsorption and oil-water separation efficiency, and EOs removal efficiency exceeded 99%. The maximum adsorption capacities were 957.0 mg/g for STAB-Sep and 1031.5 mg/g for DDAB-Sep, suggesting that modified Sep with double chains exhibited a high affinity for EOs. Both the Langmuir and the Freundlich isotherms could be used to explain the adsorption process. Thermodynamic parameters proved that the adsorption process was a spontaneous endothermic physical process. This study provides a theoretical foundation for the design of high-efficiency and low-cost organoclay adsorbents.
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