Journal
CARBOHYDRATE POLYMERS
Volume 142, Issue -, Pages 105-113Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2016.01.041
Keywords
Poly(lactic acid); Cellulose nanocrystals; Grafting; Renewable bionanocomposites; Interfacial compatibility
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Funding
- University of the Basque Country (UPV/EHU)
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Cellulose nanocrystals (CNC), extracted from microcrystalline cellulose by acid hydrolysis, were grafted by ring opening polymerization of L-Lactide initiated from the hydroxyl groups available at their surface and two different CNC:L-lactide ratios (20:80 and 5:95) were obtained. The resulting CNC-g-PLLA nanohybrids were incorporated in poly(lactic acid) (PLA) matrix by an optimized extrusion process at two different content (1 wt.% and 3 wt.%) and obtained bionanocomposite films were characterized by thermal, mechanical, optical and morphological properties. Thermal analysis showed CNC grafted with the higher ratio of lactide play a significant role as a nucleating agent. Moreover, they contribute to a significant increase in the crystallization rate of PLA, and the best efficiency was revealed with 3 wt.% of CNC-g-PLLA. This effect was confirmed by the increased in Young's modulus, suggesting the CNC graft ratio and content contribute significantly to the good dispersion in the matrix, positively affecting the final bionanocomposite properties. (C) 2016 Elsevier Ltd. All rights reserved.
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