Journal
CARBOHYDRATE POLYMERS
Volume 136, Issue -, Pages 210-215Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2015.09.047
Keywords
Polymer blends; Polyethylene; Thermoplastic starch; Recyclability
Categories
Funding
- CNPq
- CAPES
- FAPEMIG
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The great quantity of synthetic plastic discarded inappropriately in the environment is forcing the search for materials that can be reprocessable and biodegradable. Blends between synthetic polymers and natural and biodegradable polymers can be good candidates of such novel materials because they can combine processability with biodegradation and the use of renewable raw materials. However, traditional polymers usually present high levels of recyclability and use the well-established recycling infrastructure that can eventually be affected by the introduction of systems containing natural polymers. Thus, this work aims to evaluate the effect of reprocessing (simulated here by multiple extrusions) on the structure and properties of a low density polyethylene/thermoplastic starch (LDPE/TPS) blend compared to LDPE. The results indicated that multiple extrusion steps led to a reduction in the average size of the starchrich phases of LDPE/TPS blends and minor changes in the mechanical and rheological properties of the materials. Such results suggest that the LDPE/TPS blend presents similar reprocessability to the LDPE for the experimental conditions used. (C) 2015 Elsevier Ltd. All rights reserved.
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